4-[5-(Furan-2-yl)-3-trifluoro­methyl-1H-pyrazol-1-yl]benzene­sulfonamide

نویسندگان

  • Abdullah M. Asiri
  • Hassan M. Faidallah
  • Khalid A. Alamry
  • Seik Weng Ng
  • Edward R. T. Tiekink
چکیده

In the title compound, C(14)H(10)F(3)N(3)O(3)S, there are significant twists in the mol-ecule, as seen in the values of the dihedral angles between the pyrazole ring and each of the furan [31.1 (2)°] and benzene rings [55.58 (10)°]. The amino N atom occupies a position almost normal to the benzene ring [N-S-C(ar)-C(ar) (ar = aromatic) torsion angle = 83.70 (19)°]. One amino H atom forms a hydrogen bond to the tricoordinate pyrazole N atom and the other inter-acts with a sulfonamide O atom, forming a supra-molecular chain along [010]. The chains are consolidated into a supra-molecular layers via C-H⋯O inter-actions involving the second sulfonamide O atom; layers stack along [10-1]. The furan ring was found to be disordered over two diagonally opposite orientations of equal occupancy.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012